全文获取类型
收费全文 | 1018篇 |
免费 | 102篇 |
国内免费 | 51篇 |
专业分类
化学 | 154篇 |
晶体学 | 1篇 |
力学 | 77篇 |
综合类 | 34篇 |
数学 | 665篇 |
物理学 | 240篇 |
出版年
2024年 | 1篇 |
2023年 | 10篇 |
2022年 | 21篇 |
2021年 | 34篇 |
2020年 | 27篇 |
2019年 | 16篇 |
2018年 | 26篇 |
2017年 | 26篇 |
2016年 | 35篇 |
2015年 | 27篇 |
2014年 | 35篇 |
2013年 | 60篇 |
2012年 | 54篇 |
2011年 | 48篇 |
2010年 | 48篇 |
2009年 | 49篇 |
2008年 | 50篇 |
2007年 | 51篇 |
2006年 | 55篇 |
2005年 | 49篇 |
2004年 | 47篇 |
2003年 | 49篇 |
2002年 | 39篇 |
2001年 | 43篇 |
2000年 | 34篇 |
1999年 | 36篇 |
1998年 | 24篇 |
1997年 | 26篇 |
1996年 | 17篇 |
1995年 | 12篇 |
1994年 | 16篇 |
1993年 | 13篇 |
1992年 | 17篇 |
1991年 | 7篇 |
1990年 | 11篇 |
1989年 | 6篇 |
1988年 | 6篇 |
1987年 | 6篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 7篇 |
1983年 | 1篇 |
1982年 | 4篇 |
1981年 | 2篇 |
1980年 | 9篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1977年 | 1篇 |
1973年 | 2篇 |
排序方式: 共有1171条查询结果,搜索用时 31 毫秒
1.
Despite repeated calls for a thorough cleanup of water pollution in the Ganges river, there are only two papers in the social sciences by Batabyal and Beladi (2017, 2019) that have shed theoretical light on this cleanup problem and its connection to the sustainability of tourism in Varanasi. Hence, we extend the above‐mentioned analyses and focus on two specific questions. First, we introduce the notion of a safe minimum standard (SMS) into the study and show how to analyze a probabilistic model of the Ganges cleanup problem when the SMS is accounted for. Second, for a representative citizen of Varanasi, we study how the magnitude of the elasticity of substitution between a composite consumption good and water quality in the Ganges—modeled by the SMS—affects the tradeoff between consumption and water quality maintenance. 相似文献
2.
John Engbers 《Journal of Graph Theory》2017,85(4):780-787
For graphs G and H , an H‐coloring of G is a map from the vertices of G to the vertices of H that preserves edge adjacency. We consider the following extremal enumerative question: for a given H , which connected n‐vertex graph with minimum degree δ maximizes the number of H‐colorings? We show that for nonregular H and sufficiently large n , the complete bipartite graph is the unique maximizer. As a corollary, for nonregular H and sufficiently large n the graph is the unique k‐connected graph that maximizes the number of H‐colorings among all k‐connected graphs. Finally, we show that this conclusion does not hold for all regular H by exhibiting a connected n‐vertex graph with minimum degree δ that has more ‐colorings (for sufficiently large q and n ) than . 相似文献
3.
The triply bonded heavier main-group compounds have a textbook trans-bent geometry, in contrast to a familiar linear form found for the lightest analogues. Strikingly, the unexpected linear group 13 E≡E triple bonds were herein found in the D4h-symmetry E2Li62+ clusters, and they possess a large barrier (>18.0 kcal/mol) towards the dissociation of Li+. The perfectly surrounded Li4 motifs and two linear coordinated Li atoms strongly suppress the increasing nonbonded electron density of heavier E atoms, making two degenerate π bonds and one multi-center σ bond in linear heavier main-group triple bonds. The surrounding Li6 motifs not only creates an effective electronic structure to form a linear E≡E triple bond, but the resulting electrostatic interactions account for the highly stable global E2Li62+ clusters. 相似文献
4.
Development of models for prediction of the antioxidant activity of derivatives of natural compounds
Antioxidants are important for maintaining the appropriate balance between oxidizing and reducing species in the body and thus preventing oxidative stress. Many natural compounds are being screened for their possible antioxidant activity. It was found that a mushroom pigment Norbadione A, which is a pulvinic acid derivative, shows an antioxidant activity; the same was found for other pulvinic acid derivatives and structurally related coumarines. Based on the results of in vitro studies performed on these compounds as a part of this study quantitative structure–activity relationship (QSAR) predictive models were constructed using multiple linear regression, counter-propagation artificial neural networks and support vector regression (SVR). The models have been developed in accordance with current QSAR guidelines, including the assessment of the models applicability domains. A new approach for the graphical evaluation of the applicability domain for SVR models is suggested. The developed models show sufficient predictive abilities for the screening of virtual libraries for new potential antioxidants. 相似文献
5.
6.
7.
研究了两端边界均为完全约束的自然弯扭梁在小应变,大位移和大转动情况下的非线性性质,并考虑了横向剪切变形和扭转翘曲变形的影响,分析中还包括了拉伸,弯曲和扭转的各种弹性耦合。由最小势能原理可以导出所给问题的平衡方程。这里欧拉角可以用来表示任意大的转动。该方法还可方便地推广到其他各种不完全约束边界的情况。此外,利用上述结果还可以得到该梁在小位移理论中的基本方程和有关公式。 相似文献
8.
A technique for stability analysis of stringer shells is proposed. It is used to analyze the minimum critical stresses. The
dependence of the dimensionless parameters σcr/σcl on the number of stringers is plotted. The linear and nonlinear theories of ribbed shells are used to examine the features
of how stringer shells lose stability. It is shown that the minimum critical stresses determined using the theory of ribbed
shells and a structurally orthotropic model are close within the range of stiffness parameters considered
__________
Translated from Prikladnaya Mekhanika, Vol. 42, No. 2, pp. 59–64, February 2006. 相似文献
9.
ABSTRACT The theory of calculus of variations is a mathematical tool which is widely used in different scientific areas in particular in physics and chemistry. This theory is strongly related with optimisation. In fact the former seeks to optimise an integral related with some physical magnitude over some space to an extremum by varying a function of the coordinates. On the other hand, reaction paths and potential energy surfaces, in particular their stationary points, are the basis of many chemical theories, in particular reactions rate theories. We present a review where it is gathered together the variational nature of many types of reaction paths: steepest descent, Newton trajectories, artificial force induced reaction (AFIR) paths, gradient extremals, and gentlest ascent dynamics (GAD) curves. The variational basis permits to select the best optimisation technique in order to locate important theoretical objects on a potential energy surface. 相似文献
10.
Meena Kumari Upendra Kumar Singh Abbul Bashar Khan Maqsood Ahmad Malik 《Journal of Dispersion Science and Technology》2018,39(10):1462-1468
The effect of bovine serum albumin on the surface properties of IL-type gemini surfactant ([C10-4-C10im]Br2), have been investigated by surface tension method. The critical micelle concentration (CMC) as a function of BSA concentrations at various temperatures was investigated. The CMC of [C10-4-C10im]Br2 increases with increasing the concentration of BSA as well as the temperature of the system. The interfacial parameters viz; maximum surface excess concentration (Γmax), the minimum area per molecule (Amin), and surface pressure at CMC (Πcmc) were calculated. In addition, thermodynamic parameters of adsorption and micellization were evaluated by using surface tension data. The results indicated that the binding of [C10-4-C10im]Br2 to BSA is spontaneous and exothermic in nature. The process is entropy driven and hydrophobic interactions are the major driving forces. 相似文献